Joints and magnetics · Banned

Lead and standard solder joints

SnPbvalues describe: 63Sn-37Pb

Why it's out

Marginal vapor pressure, creep, and flux residues that outgas forever.

Where it hides

Ad hoc electrical joints: use crimps, spot welds, or vacuum-rated solder practice.

Properties

The values below are candidate: compiled from the sources named, not yet individually validated. Provisional provenance: O'Hanlon, A User's Guide to Vacuum Technology.

Wet cleaning

Recipeif it must be present: ultrasonic flux removal in IPA, then a long bake
Forbiddenno-clean flux, which is not vacuum-clean
Limitflux residue, which outgasses far longer than the alloy

Vacuum and outgassing

Outgassing, unbaked (10 h)5e-8 mbar·L/s/cm²
Outgassing, bakednot bakeable
Vapour pressurelead evaporates slowly above 300 °C, but the flux is the real problem

Temperature

Bake, assembled80 °C
Braze / H2 firing183 reflow °C
Metallurgical limitTHE CONDEMNING NUMBER: melts at 183 °C, so it caps the bakeout of every system it touches

Thermal

CTE25 ppm/K
Thermal conductivity50 W/m·K
Specific heat180 J/kg·K
Emissivity0.1
Melting / softening183 °C

Mechanical

Strength30–50 tens MPa
Tensile30–50 MPa
Elongation30 %
Young's modulus30 GPa
Density8.4 g/cm3

Electrical and magnetic

Relative permeability~1.0
Resistivity15 µΩ·cm

Engineering

Joiningsoldered
Process notespresent in legacy feedthroughs and assemblies
Availability and costcommodity
Sources · 1
  1. O Hanlon, A Users Guide to Vacuum Technology

← The Matter